Le Châtelier's Principle Quiz: According to Le Chatelier, What's True? (2024)

Le Châtelier's Principle Quiz: According to Le Chatelier, What's True? (3)

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18 Questions

What is the equilibrium constant for the reaction PCl5(g) ⇌ PCl3(g) + Cl2(g) if the flask at equilibrium contains 0.1 mol PCl5, 0.20 mol PCl3, and 0.20 mol Cl2?

0.02

Which compound is NOT a Brønsted-Lowry acid?

NH3

In the reaction 2 CO2(g) ⇌ 2 CO(g) + O2(g), how can the equilibrium partial pressure of CO (g) be maximized according to Le Châtelier's principle?

At high temperature and low pressure

A 0.045 M aqueous solution with a pOH of 5.33 is classified as:

weak base

For a system that absorbs 60 J of heat while 40 J of work are performed on it, then releases 30 J of heat while doing 70 J of work, what is the change in internal energy (ΔU)?

30 J

Which statement is TRUE about enthalpy?

Enthalpy is a state function.

What is the heat capacity of the water in the bomb calorimeter?

4.18 J oC−1 g−1

Which substance has the highest standard enthalpy of formation among NH3(g), HCl(g), and NH4Cl(s)?

HCl(g)

What is the equilibrium constant for the reaction NH3(g) + HCl(g) ⇌ NH4Cl(s) at 25oC?

1.39

In Le Chatelier's principle, what happens when a stress is applied to a system at equilibrium?

The system shifts to relieve the stress and re-establish equilibrium.

Which concept involves ions that do not participate in a chemical reaction but are present in the solution?

Spectator ions

What is the rest mass of a neutron?

1.675 x 1027 kg

Which of the following statements about enthalpy is correct?

H is the value of q measured under conditions of constant pressure.

For the reaction N2O4(g) + Cl2(g) → 2 NOCl(g) + O2(g), what is ΔHo?

+222.09 kJ mol-1

In the reaction 2 KCl(aq) + O2(g) → 2 KClO3(aq), which species acts as a spectator ion?

KCl(aq)

Which of the following reactions has ΔH equal to ΔH°f?

128 kJ

If a human needs 11300 kJ of energy per day, and ΔHcombustion of glucose is -5650 kJ mol–1, how many grams of glucose must be consumed per day?

200 g

What is the specific heat capacity of lead if 52 J of heat raises the temperature of a block of lead from 22°C to 32°C?

0.115 J g-1 K-1

Study Notes

Le Châtelier's Principle

  • Le Châtelier's principle predicts that the equilibrium partial pressure of CO (g) can be maximised under different conditions:
    • Low temperature and low pressure
    • High temperature and low pressure
    • High temperature and high pressure
    • Low temperature and high pressure
    • In the presence of solid carbon

Equilibrium Constant

  • The equilibrium constant (Kc) can be calculated from the concentrations of reactants and products at equilibrium:
    • Kc = [PCl3]^2 [Cl2]^2 / [PCl5]^2

Thermodynamics

  • ΔU (change in internal energy) can be calculated from the heat absorbed and work done on the system:
    • ΔU = Q - W
  • Enthalpy (H) is a state function, and ΔH is independent of the state of the reactants and products:
    • ΔH = ΔH°f (enthalpy of formation)

Calorimetry

  • The heat of combustion of octane (C8H18) can be calculated from the temperature change in a bomb calorimeter:
    • ΔHcombustion = -5650 kJ mol-1 (for glucose)

Reaction Equilibria

  • The equilibrium constant (Kc) can be calculated from the concentrations of reactants and products at equilibrium:
    • Kc = [NH4Cl] / [NH3] [HCl]
  • The reaction quotient (Q) can be calculated from the concentrations of reactants and products at any time:
    • Q = [NH4Cl] / [NH3] [HCl]

Thermodynamic Properties

  • Standard enthalpy of formation (ΔH°f) is the enthalpy change for the formation of one mole of a substance from its constituent elements:
    • ΔH°f (NH3) = -46.19 kJ mol-1
    • ΔH°f (HCl) = -92.30 kJ mol-1
    • ΔH°f (NH4Cl) = -314.4 kJ mol-1

Energy Requirements

  • A human being requires 11300 kJ of energy per day:
    • To satisfy this energy requirement, a person needs to consume a certain amount of glucose:
      • Amount of glucose = 11300 kJ / -5650 kJ mol-1 = 2 mol (approx.)

Test your understanding of Le Châtelier's principle with this quiz, focusing on predicting equilibrium conditions for a given reaction. Explore how different factors impact the equilibrium partial pressure of carbon monoxide gas in the reaction 2 CO2(g) ⇌ 2 CO(g) + O2(g).

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FAQs

What is the Le Chatelier principle quizlet? ›

Le Châtelier's principle predicts that when the pressure of an equilibrium system is increased, due to a decrease in volume, the system will shift in the direction that decreases the total moles of gas in the system to minimize the stress.

What is the answer to the equilibrium and Le Chatelier's principle? ›

Le Chatelier's principle can be stated as follows: A change in one of the variables that describe a system at equilibrium produces a shift in the position of the equilibrium that counteracts the effect of this change.

Which of the answer choices correctly describes Le Chatelier's principle? ›

Final answer: The correct description of Le Châtelier's principle is that a system at chemical equilibrium will adjust to changes by shifting in a direction to regain equilibrium.

What Le châtelier's principle tells us about how we can change the position of a reaction system at equilibrium? ›

Le Chatelier's principle implies that a pressure increase shifts an equilibrium to the side of the reaction with the fewer number of moles of gas, while a pressure decrease shifts an equilibrium to the side of the reaction with the greater number of moles of gas.

Which of the following is according to Le Chatelier's principle? ›

Le Chtelier's principle states that any change to a system at equilibrium will adjust to compensate for that change. If the pressure is increased, the position of equilibrium will move so that the pressure is reduced again.

What is the Le Chatelier principle of the experiment? ›

Le Châtelier's principle states that a system at equilibrium will respond to a stress on the system in such a way so as to relieve the stress and establish a new equilibrium.

What is the equation for Le Chatelier's principle? ›

Le Chatelier's Principle Examples

Concentration: In a system where the reaction A + B ⇌ C + D is currently in equilibrium, increasing the concentration of one of the reactants, e.g., 2 A + B ⇌ C + D , will cause a shift in equilibrium to the right.

What is the Le Chatelier principle in economics? ›

The Le Chatelier principle states that the sensitivity of input demands with respect to own price variations is smaller when the output level is held constant than when it is adjusted.

What is the Le Chatelier's principle of reaction rates and equilibrium? ›

Le Chatelier's principle predicts that equilibrium will shift to decrease the concentration of reactants. Increasing the rate of the forward reaction will mean a decrease in reactants. So some of the sulfur dioxide or oxygen is used to produce sulfur trioxide.

Which is the best statement about Le Chatelier's principle? ›

The best description of Le Chatelier's Principle is option C) a reaction which is at equilibrium, when disturbed, will react appropriately to reestablish equilibrium.

What happens when the Le Chatelier's principle occurs? ›

According to Le Chatelier's principle, when the concentration of a product is reduced in a chemical reaction that was in equilibrium The equilibrium shifts to the right to favor the formation of products.

Which of the following states Le Chatelier's principle quizlet? ›

What does Le Chatelier's Principle state? When stress is applied to a system, the system will try to relieve the stress.

What is the Le Chatelier's principle statement? ›

Le Chatelier's principle states that if a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium shifts to counteract the change to reestablish an equilibrium.

What is the Le Chatelier's principle for dummies? ›

The conditions of a chemical system in equilibrium can change. Le Chatlier's principle says a system at equilibrium responds to changes in predictable ways. The response to a change always occur in a direction that reestablishes equilibrium. And the response to a change always opposes the change to the system.

What does Le châtelier's principle state Brainly? ›

Le Châtelier's principle states that when a system at equilibrium is subjected to a change in conditions, it will respond by shifting in a way that helps counteract the change and restore equilibrium. In other words, the equilibrium position of a reaction will shift in order to reduce the effect of the imposed change.

What is the De Chatelier principle? ›

General statements of Le Chatelier's principle

It states that changes in the temperature, pressure, volume, or concentration of a system will result in predictable and opposing changes in the system in order to achieve a new equilibrium state.

What is Le Chatelier's principle and why is it important? ›

Le Chatelier's Principle helps to predict what effect a change in temperature, concentration or pressure will have on the position of the equilibrium in a chemical reaction. This is very important, particularly in industrial applications, where yields must be accurately predicted and maximised.

What is Le Chatelier known for? ›

His most important discovery, Le Chatelier's principle, was made in 1884. This simply states that any change made in a system of equilibrium results in a shift of the equilibrium in the direction that minimizes the change.

Which can be explained as applications of Le Chatelier principle? ›

Many industrial processes use Le Chatelier's principle to help increase yield but often use compromise conditions. These balance high yield with cost and rate of reaction. Methanol, ethanol, sulphuric acid and ammonia production are all examples of reversible reactions in industry that use Le Chatelier's principle.

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